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Martinez, Michael R.; Zhuang, Ziye; Treichel, Megan; Cuthbert, Julia; Sun, Mingkang; Pietrasik, Joanna; Matyjaszewski, Krzysztof (, Polymers)Model poly(n-butyl acrylate) (PBA) networks were prepared by photoinduced atom transfer radical polymerization (photoATRP), followed by curing of polymer stars via atom transfer radical coupling (ATRC) with a nitrosobenzene radical trap. The resulting nitroxyl radical installed thermally labile alkoxyamine functional groups at the junctions of the network. The alkoxyamine crosslinks of the network were degraded back to star-like products upon exposure to temperatures above 135 °C. Characterization of the degraded products via gel permeation chromatography (GPC) confirmed the inversion of polymer topology after thermal treatment.more » « less
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Wang, Zongyu; Lee, Jaejun; Wang, Zhenhua; Zhao, Yuqi; Yan, Jiajun; Lin, Yu; Li, Sipei; Liu, Tong; Olszewski, Mateusz; Pietrasik, Joanna; et al (, ACS Macro Letters)null (Ed.)
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Turczyńska, Karolina; Rahimi, Mahdi; Charmi, Gholamreza; Pham, Duy_Anh; Murata, Hironobu; Kozanecki, Marcin; Filipczak, Paulina; Ulański, Jacek; Diem, Tadeusz; Matyjaszewski, Krzysztof; et al (, ACS Applied Materials & Interfaces)
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Zhao, Yepin; Wang, Zongyu; Yuan, Rui; Lin, Yu; Yan, Jiajun; Zhang, Jianan; Lu, Zhao; Luo, Danli; Pietrasik, Joanna; Bockstaller, Michael R.; et al (, Polymer)
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